2009-06-06 02:08:04 (0f3b9e12): Scanned 0 songs (was 0) in 0 seconds
The line above shows that firefly found no songs.
If the permissions of the songs are wrong, Firefly will not being able to read the songs.
2009-06-06 02:08:04 (0f3b9e12): Scanning for MP3s in C:Documents and SettingsAdministratorMy DocumentsMy Music
Also, how sure are you that the songs are in the correct directory? You have music placed (.mp3) in the above directory?